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Technical Paper

Further Development of an On-Board Distillation System for Generating a Highly Volatile Cold-Start Fuel

2005-04-11
2005-01-0233
The On-Board Distillation System (OBDS) extracts, from gasoline, a highly volatile crank fuel that enables simultaneous reduction of start-up fuel enrichment and significant ignition timing retard during cold-starting. In a previous paper we reported reductions in catalyst light-off time of >50% and THC emissions reductions >50% over Phase I of the FTP drive cycle. The research presented herein is a further development of the OBDS concept. For this work, OBDS was improved to yield higher-quality start-up fuel. The PCM calibration was changed as well, in order to improve the response to intake manifold pressure transients. The test vehicle was tested over the 3-phase FTP, with exhaust gases speciated to determine NMOG and exhaust toxics emissions. Also, the effectiveness of OBDS at generating a suitable starting fuel from a high driveability index test gasoline was evaluated.
Technical Paper

A Global Reaction Model for the HCCI Combustion Process

2004-10-25
2004-01-2950
This paper presents a new global reaction model to simulate the Homogeneous Charge Compression Ignition (HCCI) combustion process. The model utilizes seven equations and seven active species. The model includes five reactions that represent degenerate chain branching in the low temperature region, including chain propagation, termination and branching reactions and the reaction of HOOH at the second stage ignition. Two reactions govern the high temperature oxidation, to allow formation and prediction of CO, CO2, and H2O. Thermodynamic parameters were introduced through the enthalpy of formation of each species. We were able to select the rate parameters of the global model to correctly predict the autoignition delay time at constant density for n-heptane and iso-octane, including the effect of equivalence ratio.
Technical Paper

From Spark Plugs to Railplugs – The Characteristics of a New Ignition System

2004-10-25
2004-01-2978
Ignition of extremely lean or dilute mixtures is a very challenging problem. Therefore, it is essential for the engine development engineer to understand the fundamentals and limitations of existing ignition systems. This paper presents a new railplug ignition concept, a high-energy ignition system, which can enhance ignition of very lean mixtures by means of its high-energy deposition and high velocity jet of the plasma. This paper presents initial results of tests using an inductive ignition system, a capacitor discharge ignition system, and a railplug high-energy ignition system. Discharge characteristics, such as time-resolved voltage, current, and luminous emission were measured. Spark plug and railplug ignition are compared for their effects on combustion stability of a natural gas engine. The results show that railplugs have a very strong arc-phase that can ensure the ignition of very dilute mixtures.
Technical Paper

Some Observations on the Effects of EGR, Oxygen Concentration, and Engine Speed on the Homogeneous Charge Combustion of n-Heptane

2004-06-08
2004-01-1905
NOx and soot emissions remain critical issues in diesel engines. One method to address these problems is to achieve homogeneous combustion at lower peak temperatures - the goal of research on controlled autoignition. In this paper n-heptane is used to represent a large hydrocarbon fuel and some of the effects of internal and external EGR, oxygen concentration, and engine speed on its combustion have been examined through simulation and experiment. Simulations were conducted using our existing skeletal chemical kinetic model, which combines the chemistry of the low, intermediate, and high temperature regimes. Experiments were carried out in a single cylinder, four-stroke, air cooled engine and a single cylinder, two stroke, water cooled engine. In the four-stroke engine experiments the effects of EGR were examined using heated N2 addition as a surrogate for external EGR and engine modifications to increase internal EGR.
Technical Paper

The Texas Diesel Fuels Project, Part 3: Cost-Effectiveness Analyses for an Emulsified Diesel Fuel for Highway Construction Equipment Fleets

2004-03-08
2004-01-0086
The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel as an emissions control measure in July 2002. They initiated a study of the effectiveness of this fuel in comparison to conventional diesel fuel for TxDOT's Houston District operations and included the fleet operated by the Associated General Contractors (AGC) in the Houston area. Cost-effectiveness analyses, including the incremental cost per ton of NOx removed, were performed. NOx removal was the focus of this study because Houston is an ozone nonattainment area, and NOx is believed to be the limiting factor in ozone formation in the Houston area. The cost factors accounted for in the cost-effectiveness analyses included the incremental cost of the fuel (including an available rebate from the State of Texas), the cost of refueling more often, implementation costs, productivity costs, maintenance costs, and various costs associated with the tendency of the emulsion to separate.
Technical Paper

Impact of Railplug Circuit Parameters on Energy Deposition and Durability

2003-10-27
2003-01-3135
A railplug is a new type of ignitor for SI engines. A model for optimizing energy deposition in a railplug ignition system is developed. The model is experimentally validated using a low voltage railplug ignition circuit. The effect of various ignition circuit parameters on the energy deposition and its rate are discussed. Durability of railplugs is an important factor in railplug circuit design. As for all spark ignitors, durability of a railplug decreases as energy deposition is increased. Therefore recommendations are made to minimize wear and increase durability, while depositing sufficient energy to attain ignition, using a railplug.
Technical Paper

Direct Measurement of Powertrain Component Efficiencies for a Light-Duty Vehicle with a CVT Operating Over a Driving Cycle

2003-10-27
2003-01-3202
In order to determine the factors that affect fuel economy quantitatively, the power flows through the major powertrain components were measured during operation over transient cycles. The fuel consumption rate and torque and speed of the engine output and axle shafts were measured to assess the power flows in a vehicle with a CVT. The measured power flows were converted to energy loss for each component to get the efficiency. Tests were done at Phase 1 and Phase 3 of the FTP and for two different CVT shift modes. The measured energy distributions were compared with those from the ADVISOR simulation and to results from the PNGV study. For both the Hot 505 and the Cold 505, and for both shift modes, the major powertrain loss occurs in the engine, including or excluding standby losses. However, the efficiency of the drivetrain/transmission is important because it influences the efficiency of the engine.
Technical Paper

A Skeletal Chemical Kinetic Model for the HCCI Combustion Process

2002-03-04
2002-01-0423
In Homogeneous Charge Compression Ignition (HCCI) engines, fuel oxidation chemistry determines the auto-ignition timing, the heat release, the reaction intermediates, and the ultimate products of combustion. Therefore a model that correctly simulates fuel oxidation at these conditions would be a useful design tool. Detailed models of hydrocarbon fuel oxidation, consisting of hundreds of chemical species and thousands of reactions, when coupled with engine transport process models, require tremendous computational resources. A way to lessen the burden is to use a “skeletal” reaction model, containing only tens of species and reactions. This paper reports an initial effort to extend our skeletal chemical kinetic model of pre-ignition through the entire HCCI combustion process. The model was developed from our existing preignition model, which has 29 reactions and 20 active species, to yield a new model with 69 reactions and 45 active species.
Technical Paper

Effects of In-cylinder Flow on Fuel Concentration at the Spark Plug, Engine Performance and Emissions in a DISI Engine

2002-03-04
2002-01-0831
A fiber optic instrumented spark plug was used to make time-resolved measurements of the fuel vapor concentration history near the spark gap in a four-valve DISI engine. Four different bulk flow were investigated. Several early and late injection timings were examined. The fuel concentration at the spark gap was correlated with IMEP. Emissions of CO, HCs, and NOx were related to the type of bulk flow. For both early and late injection the CoVs of fuel concentration were generally lowest for the weakest bulk flow which resulted in a stable stratification. Strong bulk flows convected the inhomogeneities through the measurement area near the spark plug resulting in both large intracycle and cycle-to-cycle variation in equivalence ratio at the time of ignition.
Technical Paper

Effects of Piston Wetting on Size and Mass of Particulate Matter Emissions in a DISI Engine

2002-03-04
2002-01-1140
We have examined the influence of piston wetting on the size distribution and mass of particulate matter (PM) emissions in a SI engine using several different fuels. Piston wetting was isolated as a source of PM emissions by injecting known amounts of liquid fuel onto the piston top using an injector probe. The engine was run predominantly on propane with approximately 10% of the fuel injected as liquid onto the piston. The liquid fuels were chosen to examine the effects of fuel volatility and molecular structure on the PM emissions. A nephelometer was used to characterize the PM emissions. Mass measurements from the nephelometer were compared with gravimetric filter measurements, and particulate size measurements were compared with scanning electron microscope (SEM) photos of particulates captured on filters. The engine was run at 1500 rpm at the Ford world-wide mapping point with an overall equivalence ratio of 0.9.
Technical Paper

Effects of Fuel Volatility, Load, and Speed on HC Emissions Due to Piston Wetting

2001-05-07
2001-01-2024
Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.
Technical Paper

Particulate Characterization of a DISI Research Engine using a Nephelometer and In-Cylinder Visualization

2001-05-07
2001-01-1976
A nephelometer system was developed to characterize engine particulate emissions from DISI engines. Results were correlated with images showing the location and history of particulates in the cylinder of an optical engine. The nephelometer's operation is based upon the dependence of scattered laser light on particulate size from a flow sampled from the exhaust of an engine. The nephelometer simultaneously measured the scattered light from angles of 20° to 160° from the forward scattering direction in 4° increments. The angular scattering measurements were then compared with calculations using a Mie scattering code to infer information regarding particulate size. Measurements of particulate mass were made based upon a correlation developed between the scattered light intensity and particulate mass samples trapped in a 0.2-micron filter. Measurements were made in a direct injection single-cylinder spark ignition research engine having a transparent quartz cylinder.
Technical Paper

Refinement of a Dedicated E85 1999 Silverado with Emphasis on Cold Start and Cold Drivability

2001-03-05
2001-01-0679
The University of Texas 2000 Ethanol Vehicle Challenge team remains focused on cold start, cold drivability, fuel economy, and emissions reduction for our 2000 Ethanol Vehicle Challenge entry. We used the stock PCM for all control functions except control of an innovative cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, use of a moddified version of the California Emissions Calibrated PCM, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. Additionally, we eliminated EGR at high load to improve power density. Major modifications, such as increasing the compression ratio or pressure boosting, were eliminated from consideration due to cost, complexity, reliability, or emissions penalties.
Technical Paper

The Effects of Fuel Volatility and Structure on HC Emissions from Piston Wetting in DISI Engines

2001-03-05
2001-01-1205
Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.
Technical Paper

Liquid Film Evaporation Off the Piston of a Direct Injection Gasoline Engine

2001-03-05
2001-01-1204
An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.
Technical Paper

Prediction of Pre-ignition Reactivity and Ignition Delay for HCCI Using a Reduced Chemical Kinetic Model

2001-03-05
2001-01-1025
Homogeneous Charge Compression Ignition (HCCI) engines have the possibility of low NOx and particulate emissions and high fuel efficiencies. In HCCI the oxidation chemistry determines the auto-ignition timing, the heat release rate, the reaction intermediates, and the ultimate products of combustion. This paper reports an initial effort to apply our reduced chemical kinetic model to HCCI processes. The model was developed to study the pre-ignition characteristics (pre-ignition heat release and start of ignition) of primary reference fuels (PRF) and includes 29 reactions and 20 active species. The only modifications to the model were to make the proscribed adjustments to the fuel specific rate constants, and to enhance the H2O2 decomposition rate to agree with published data.
Technical Paper

In-Situ Mapping and Analysis of the Toyota Prius HEV Engine

2000-08-21
2000-01-3096
The Prius is a major achievement by Toyota: it is the first mass-produced HEV with the first available HEV-optimized engine. Argonne National Laboratory's Advanced Powertrain Test Facility has been testing the Prius for model validation and technology performance and assessment. A significant part of the Prius test program is focused on testing and mapping the engine. A short-length torque sensor was installed in the powertrain in-situ. The torque sensor data allow insight into vehicle operational strategy, engine utilization, engine efficiency, and specific emissions. This paper describes the design and process necessary to install a torque sensor in a vehicle and shows the high-fidelity data measured during chassis dynamometer testing. The engine was found to have a maximum thermodynamic efficiency of 36.4%. Emissions and catalyst efficiency maps were also produced.
Technical Paper

Effects of Fuel Parameters on FTP Emissions of a 1998 Toyota with a Direct Injection Spark Ignition Engine

2000-06-19
2000-01-1907
The effects of fuel properties on the emissions of a production vehicle with a gasoline direct injection engine operating over the Federal Test Procedure (FTP) cycle were investigated. The vehicle used was a 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine. Engine-out and tailpipe FTP emissions for six fuels and a California Phase 2 RFG reference fuel are presented. Four of the test fuels were blended from refinery components to meet specified distillation profiles. The remaining test fuels were iso-octane and toluene, an iso-alkane and an aromatic with essentially the same boiling point (at atmospheric pressure) that is near the T50 point for the blended fuels. Statistically significant effects, at the 95% confidence level, of the fuels on tailpipe emissions were found. Correlations were sought between the properties of the five blends and the Emissions Indices for engine-out hydrocarbons and NOx and for tailpipe particulates.
Technical Paper

Effect of Fuel Parameters on Emissions from a Direct Injection Spark Ignition Engine During Constant Speed, Variable Load Tests

2000-06-19
2000-01-1909
A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. These seven fuels can be divided into groups for examination of the effects of volatility, MTBE, and structure (an aromatic versus an i-alkane). Correlations between the fuel properties and their effects on emissions are presented. Use of steady state tests rather than driving cycles to examine fuel effects on emissions eliminates the complications resulting from accelerations, decelerations, and changes of injection timing but care had to be taken to account for the periodic regenerations of the lean NOx trap/catalyst.
Technical Paper

Tracer Fuel Injection Studies on Exhaust Port Hydrocarbon Oxidation: Part II

2000-06-19
2000-01-1945
Recently, studies were conducted on a single cylinder, four stroke engine to investigate the effect of temperature and local mixedness on exhaust port hydrocarbon oxidation. To examine the effect of temperature, hydrocarbon tracers (propane, propene, 1-butene, n-butane, and n-pentane) were individually injected into the exhaust port just behind the exhaust valve for operating conditions that provided different exhaust port temperatures. For the local mixedness experiments, tracer mixtures (propane + n-butane, 1-butene + n-butane, propene + n-butane) were injected into the exhaust port just behind either a normal exhaust valve or a shrouded exhaust valve. The concentration of tracers and their reaction products were measured using gas chromatography of samples withdrawn from the exhaust stream. The tracer consumption behavior with changing port temperature confirmed that there is a minimum port temperature for hydrocarbon oxidation.
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